drdre89 the DF64 Gen 2 don’t have DLC burrs (hope this does not appear pedantic) but rather an uncoated version of the DF DLC burrs that come with the DF64V. Both being DF 64mm burrs, only one being coated with the “Diamond Like Coating” that Gorilla Gear also use.
To answer your question though, I find (personal opninion, subjective etcetera) that the Mazzer 151B espesso burrs that come with the Duo offer a very traditional, smooth and inoffensive espresso. Silky smooth in fact. By comparision, the DF64 Gen 2 DF uncoasted burrs produce a stronger flavor - brighter with nut-like notes. Not better or worse than the Mazzer but distinctly different.
The BIG suprise for me was that the DLC version of exactly the same DF burr set (as in the DF54 Gen 2) offer more choc-like flavors and are especially well suited to milk based espresso.
My picks of those 3 burrs: Mazzer 151B for light or medium light espresso, DF DLC for choc-like milk based and DF uncoated for nut-like milk based.
And that’s why everyone needs at least two grinders, and three if they enjoy filter as well as espresso!